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• W1992358116 abstract "Hg-based (Hg,M)-1222 cuprates (Hg0.75M0.25)Sr2(Gd1.5Ce0.5)Cu2Oz (M=W, Mo, V, Cr, Ti) have been synthesized using the precursor Sr2(Gd1.5Ce0.5)Cu2Oz prepared by solid state reaction and citrate sol–gel process, respectively. X-ray powder diffraction indicates that the samples prepared by sol–gel process have better crystallization comparing with the solid state reaction. The citrate sol–gel process was improved by using diffluent Ce(NO3)3 to replace CeO2 which is almost insoluble in nitric acid and pure (Hg,M)-1222 phase was obtained. Superconductivity was observed in the (Hg0.75M0.25)Sr2(Gd1.5Ce0.5)Cu2Oz phase with M=W, Mo. Annealing under high oxygen pressure has apparently decreased the resistivity and improved Tc for (Hg,M)-1222 (M=W, Mo) samples." @default.
• W1992358116 created "2016-06-24" @default.
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• W1992358116 date "2001-07-01" @default.
• W1992358116 modified "2023-10-01" @default.
• W1992358116 title "Synthesis and superconductivity study for (Hg,M)-1222 phase (M=W, Mo, V, Cr, Ti)" @default.
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• W1992358116 doi "https://doi.org/10.1016/s0921-4534(01)00151-4" @default.
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