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- W1992364692 abstract "SUMMARYPreliminary studies using 27Al n.m.r. of well characterized size fractions containing imogolite from an Andosol are reported. They demonstrate that 27Al n.m.r. is a useful complementary tool to X-ray fluorescence methods for the detection of four-and six-fold co-ordination of aluminium in soils. Whereas the X-ray method depends on interpolating between standards, this is unnecessary in the n.m.r. method since four- and six-fold coordinated aluminium are clearly resolved. The results demonstrate how aluminium co-ordination changes in size fractions from the Andosol and confirm that all aluminium in imogolite is in six-fold co-ordination. It is also suggested that the Al-O bond distance in imogolite is 1.82 A." @default.
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- W1992364692 date "1984-06-01" @default.
- W1992364692 modified "2023-10-16" @default.
- W1992364692 title "Detection of aluminium coordination in soils and clay fractions using27 Al magic angle spinning n.m.r." @default.
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- W1992364692 doi "https://doi.org/10.1111/j.1365-2389.1984.tb00275.x" @default.
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