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- W1992371710 abstract "L acide perchlorique dans l'acide acétique réagit avec le phénylacétylène pour donner l'acetophenone, l'α-chloroacétophénone, l'αα'dichloroacétophenone, l'α-acetoxy-α'-chloroacétophénone, l'αβ-dichlorostyrène, et le β-chlorophénylacétylene La vitesse de disparition du phénylacétylène est proportionnelleàla concentration en phénylacétylène et acide perchlonque; la vitesse de consommation de l'acide perchlorique est proportionnelle aux concentrations en phénylacétylène et acide perchlorique. Le rapport des constantes de vitesse est d'environ 2,5. Les différents produits chlorés s'expliquent par la formation de perchlorate d'acétyle Perchloric acid in acetic acid reacts with phenylacetylene to yield acetophenone α-chloroacetophenone, αα'-dichloroacetophenone, α-acetoxy-α'-chloroacetophenone, dichloroαβstyrene and β-chlorophenylacetylene. The disappearance rate of phenylacetylene is proportional to the concentrations of phenylacetylene and perchloric acid; that of perchloric acid varies in proportion to the amount of phenylacetylene and perchloric acid. Rate constants are in a ratio 2.5:1. The various chlorinated products arise from acetyl perchlorate." @default.
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- W1992371710 date "1980-01-01" @default.
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- W1992371710 title "Reactions du phenylacetylene avec le melange anhydre acide acetique-acide perchlorique" @default.
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