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- W1992403077 abstract "Dispersions of the polyaniline emeraldine salt (ES) of paratoluene sulphonic acid (PAni-pTS) effectively inhibit filiform corrosion (FFC) affecting polyvinyl butyral (PVB) coated AA2024-T3 aluminium alloy. An in-situ scanning Kelvin probe (SKP) technique is used to study the effect of systematically varying PAni-pTS volume fraction (ϕpa) on FFC initiation and propagation. For ϕpa < 0.15, there is no evidence of FFC inhibition and Ecorr values recorded for the intact coated aluminium (Eintact) remain similar to those measured for unpigmented PVB. At ϕpa ≥ 0.15, a marked rise in Eintact is observed, FFC propagation rates decrease and significant oxide growth is observed at the coating-metal interface. For emeraldine base (PAni-EB)-containing coatings, there is no evidence of interfacial oxide film formation, no ennoblement of Eintact and minimal inhibition of FFC. Conversely, when a PAni-pTS induced oxide covered surface is re-coated using unpigmented PVB and FFC is initiated as per normal, a substantial reduction in the rate of FFC propagation is observed. It is therefore proposed that inhibition of FFC by PAni-pTS arises principally as a result of the protective nature of the oxide film formed at the metal-coating interface." @default.
- W1992403077 created "2016-06-24" @default.
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- W1992403077 date "2009-07-01" @default.
- W1992403077 modified "2023-09-25" @default.
- W1992403077 title "Polyaniline inhibition of filiform corrosion on organic coated AA2024-T3" @default.
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- W1992403077 doi "https://doi.org/10.1016/j.electacta.2009.02.077" @default.
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