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• W1992434932 endingPage "3880" @default.
• W1992434932 startingPage "3873" @default.
• W1992434932 abstract "Two six-coordinated manganese(II) complexes [Mn(pydien)Cl](ClO4) · C2H5OH (1), [Mn(pydien)NCS](ClO4) (2) and two seven-coordinated manganese(II) complexes [Mn(pydado)Cl](ClO4) (3), [Mn(pydado)NCS](ClO4) (4) have been obtained using linear penta and hexadentate ligands pydien and pydado (pydien: 1,7-bis(2-pyridylmethyl)-1,4,7-triazaheptane and pydado: 1,10-bis(pyridylmethyl)-1,10-diaza-4,7-dioxadecane). The crystal structures for all compounds have been determined. 1 and 3 crystallize in the triclinic space group P1¯, 2 crystallizes in the orthorhombic space group Pbca, whereas 4 crystallizes in the monoclinic space group P21/c. The bound anion (chloro or isothiocyanato) in complexes 1 and 2 has no influence on the geometry of six-coordinate manganese(II) complexes, whereas the geometry and the wrapping of the hexadentate ligand (pydado) around Mn2+ cation depend on the nature of the bound anion. The complex 3 has a capped octahedron geometry with the two pyridyl groups in trans position, while the geometry of complex 4 can be described as pentagonal bipyramid with one pyridyl group and a thiocyanate anion in the axial positions." @default.
• W1992434932 created "2016-06-24" @default.
• W1992434932 creator A5045935510 @default.
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• W1992434932 date "2005-09-01" @default.
• W1992434932 modified "2023-09-27" @default.
• W1992434932 title "Crystal structure of six and seven coordinate manganese(II) complexes with penta and hexadentate pyridylmethyl ligands" @default.
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• W1992434932 doi "https://doi.org/10.1016/j.ica.2005.06.050" @default.
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