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- W1992441003 abstract "Abstract Nitration in position C-8 of diosmetin, an easily available citroflavonoid, was studied in order to gain access to original analogs. The one-step nitration proved impossible, as mono or di-nitration on C-2′ and C-6′ positions on the lateral B ring of the molecule was exclusively observed. This surprisingly straightforward di-nitration of ring B, showing a lack of reactivity of ring A despite its high activation, has never been mentioned to date. Nitration in position C-8 was therefore performed in five steps, requiring selective deactivation of ring B." @default.
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- W1992441003 date "2010-02-01" @default.
- W1992441003 modified "2023-09-25" @default.
- W1992441003 title "Unexpected B-ring regioselective di-nitration of diosmetin, a Citrus flavonoid" @default.
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- W1992441003 doi "https://doi.org/10.1016/j.tetlet.2009.12.062" @default.
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