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- W1992458650 abstract "Mixed-metal cluster Cp4Ni2Mo2(μ3-CPh)2(μ3-CO)2 (I), in which the carbyne bridges under the “butterfly” Mo2Ni2 (Mo-M 2.674(2), Mo-Ni 2.664(2) A) wings are formed due to splitting of the CC bonds, has been synthesized by reaction of CP2Ni2(Ph2C2) and Cp2Mo2(CO)6 in refluxing o-xylene and characterized by X-ray structural analysis. In the reaction of CpNiCo(CO)3(Ph2C2) with CP2Mo2(CO)6, the tolan (diphenylacetylene) molecule is transferred with formation of the well known CP2Mo2(CO)4(Ph2C2). An unusual seven-nuclear diamagnetic cluster CP4Mo4(μ3-OH)(μ3-CPh)2(μ6-C)CO3(μ-CO)3(CO)3 (III) in which the simultaneous rupture of CC and CC bonds takes place has been synthesized by reaction of CO2(CO)6(Ph2C2) with Cp2Mo2(CO)6 in refluxing o-xylene. Cluster III is a combination of the distorted tetrahedral Cp4Mo4(μ3-CPh)2(μ-OH) (Mo-Mo 2.761(4)–2.939(4) A) and triangular Co3(μ-CO)3(Co)3 (Co-Co 2.463(3) A) fragments bonded by μ6-carbide bridges and CoMo bonds (2.909(6)–2.946(5) A)." @default.
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- W1992458650 date "1992-05-01" @default.
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- W1992458650 title "Rupture of the triple CC and CO bonds in the mixed-metal clusters with Ni2Mo2 and MO4Co3 cores. Synthesis and molecular structures of Cp4Ni2Mo2(μ3-CPh)2(μ3-CO)2 and Cp4Mo4(μ3-OH)(μ3-CPh)2(μ6-C)Co3(μ-CO)3(CO)3" @default.
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- W1992458650 doi "https://doi.org/10.1016/0022-328x(92)83321-8" @default.
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