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- W1992508321 abstract "We have successfully immobilized phosphotungstic acid (PTA), a polyoxometalate, on the surface of boron-doped diamond (BDD) surface through electrostatic self-assembly of PTA on pyridinium dye-functionalized-BDD. The inorganic/organic bilayer structure on BDD is found to exhibit fast surface-confined reversible electron transfer. The molecular dye-grafted BDD can undergo controllable electrical stripping and regeneration of PTA which can be useful for electronics or sensing applications. Furthermore, we have demonstrated the use of PTA as a molecular switch in which the direction of photocurrent from diamond to methyl viologen is reversed by the surface bound PTA. Robust photocurrent converter based on such molecular system-diamond platform can operate in corrosive medium which is not tolerated by indium tin oxide electrodes." @default.
- W1992508321 created "2016-06-24" @default.
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- W1992508321 date "2009-12-02" @default.
- W1992508321 modified "2023-10-15" @default.
- W1992508321 title "Electrostatically Self-Assembled Polyoxometalates on Molecular-Dye-Functionalized Diamond" @default.
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- W1992508321 doi "https://doi.org/10.1021/ja908131t" @default.
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