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• W1992508447 endingPage "970" @default.
• W1992508447 startingPage "959" @default.
• W1992508447 abstract "As shown by direct and redox catalysis electrochemical methods, the cation A+ (NAD+) and the dimer A2 form a chemically reversible redox couple, but with a large separation between the effective reduction potential of A+ and the oxidation potential of A2. One cause of this large separation is that the reduction of A+ into A2 involves the irreversible radical-radical dimerization of two A. radicals whereas the oxidation of A2 into 2A+ involves the irreversible cleavage of the cation radical A2.+ into A+ and A.. The reduction of A+ is kinetically controlled by dimerization of the A. radicals. In contrast, mixed kinetic control by electron transfer and cleavage or total control by electron transfer is observed in the oxidation of A2." @default.
• W1992508447 created "2016-06-24" @default.
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• W1992508447 date "1992-01-01" @default.
• W1992508447 modified "2023-09-30" @default.
• W1992508447 title "Electrochemistry of synthetic analogues of NAD dimers" @default.
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• W1992508447 doi "https://doi.org/10.1016/0022-0728(92)85017-w" @default.
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