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- W1992534811 abstract "In order to test the hypothesis that unusual fatty acids related biogenetically in structure to pulvilloric acid can be detected, the fatty acid composition of Penicillium pulvillorum was determined. GLC analysis of the mycelial fatty acid methyl esters, removed by several extractive procedures, revealed that the major fatty acids are: linoleic, palmitic, oleic, and stearic acids. These are followed by pentadecanoic, heptadecanoic, myristic, palmitoleic, isostearic, isopalmitic and linolenic acids, in decreasing concentration. 4-Methylmyristic and 4-methyllauric acids, for which convenient syntheses via 2-acyl-4-methyl-1-morpholino-1-cyclohexenes were developed, and 2-methyllauric acid, were however absent from the fatty acid spectrum. These data imply that hypothetical, single-chain, methylated polyketide precursors to pulvilloric acid are not integrated into the fatty acid biosynthetic pathway. d-Mannitol and ergosterol were also isolated from the mycelial extracts. A crystalline, apparently homogeneous material provisionally assigned in structure as a glyceride, was obtained from the beer when P. pulvillorum was grown on a special medium. Saponification followed by GLC analysis of the component fatty acid methyl esters again failed to reveal anticipated novel components. That the parental glyceride is a mixture follows from the demonstration that lauric, palmitic and stearic acids were present in a 1:1:2 ratio." @default.
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- W1992534811 date "1968-01-01" @default.
- W1992534811 modified "2023-09-25" @default.
- W1992534811 title "The fatty acids of Penicillium pulvillorum" @default.
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- W1992534811 doi "https://doi.org/10.1016/0003-9861(68)90211-7" @default.
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