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- W1992536985 abstract "We describe neutron scattering studies of the structure and dynamics of C60-fullerite. Above the order-disorder phase transition temperature, Tc, diffraction and quasielastic scattering measurements indicate that the molecules are constantly reorienting while their centers remain on a face-centered cubic lattice. Below Tc the molecules are orientationally ordered with four molecules per unit cell. Recent diffraction results suggest that any given molecule occupies one of two possible orientations with unequal probability, and inelastic scattering measurements show that the molecules librate about their equilibrium orientations. The librational amplitude becomes large as the phase transition is approached. Pulsed source measurements yield direct information regarding the structure of the C60 molecule and also support the low temperature two-orientation model. High energy inelastic studies of undoped and alkali metal-doped buckminsterfullerene provide detailed information about intramolecular vibrational frequencies and point to the important role of specific modes in promoting superconductivity at low temperatures." @default.
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- W1992536985 date "1992-11-01" @default.
- W1992536985 modified "2023-10-14" @default.
- W1992536985 title "Neutron scattering studies of C60 and its compounds" @default.
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- W1992536985 doi "https://doi.org/10.1016/0022-3697(92)90232-3" @default.
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