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- W1992540883 abstract "In this work, we were able to synthesize, in good isolated yields, seven R(+)-limonene derived amines (five of that described for the first time) employing a rhodium catalysed hydroaminomethylation reaction. This protocol consists in an one-pot three step reaction: double bond hydroformylation, aldehyde/amine condensation and imine/enamine hydrogenation. Hydroaminomethylation, besides the high yields, has a high atom economy because just 1 mol of water is wasted per mol of limonene. Due to our catalytic optimizations, the reaction time was reduced from 48 h (described in the literature) to 10–24 h, as well as limonene isomerization was strongly minimized by the triphenylphosphine added." @default.
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- W1992540883 date "2008-03-01" @default.
- W1992540883 modified "2023-10-18" @default.
- W1992540883 title "One-pot synthesis of secondary and tertiary amines from R(+)-limonene by tandem hydroformylation/reductive amination (hydroaminomethylation)" @default.
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- W1992540883 doi "https://doi.org/10.1016/j.catcom.2007.10.008" @default.
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