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- W1992585541 abstract "Lead zirconate is a room temperature antiferroelectric material, which exhibits double polarization hysteresis characteristic in the presence of external field. A transformation from antiferroelectric to paraelectric behavior through a ferroelectric phase has been exhibited upon addition of La-to pure lead zirconate thin films, which were confirmed from dielectric, hysteresis and pyroelectric and micro Raman analyses. Thin films of pure and La-modified lead zirconate were processed using A-site vacancy formula Pb(l−1.5x)LaXZrO3 by pulsed excimer laser ablation technique. Pyroelectric coefficient increased gradually from 55 to 190 μC cm−2 K−1 with the addition of 0 to 9 mole% of La to pure lead zirconate. The transition temperature has been reduced to room temperature (∼34 °C) with addition of a 9 mole% of La-to lead zirconate. Presence of antiferroelectricity in pure lead zirconate thin films is due to antiparallel shifts of Pb-ions in (110) direction and reduction of transition temperature is attributed to creation of A-site vacancies would have caused enhancing of ferro-and paraelectric behavior with La-addition." @default.
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- W1992585541 date "2002-01-01" @default.
- W1992585541 modified "2023-09-23" @default.
- W1992585541 title "Dielectric properties of La-modified antiferroelectric PbZrO3 thin films" @default.
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- W1992585541 doi "https://doi.org/10.1016/s0921-5107(01)00744-9" @default.
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