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• W1992628850 endingPage "8286" @default.
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• W1992628850 abstract "The optical response of four new anthracenylmethyl pendant-arm derivatives (L1−L4) of the macrocyclic ligands [12]aneNS3, [12]aneNS2O, [15]aneNS2O2, and [12]aneN2SO toward the metal ions Zn2+, Cd2+, Pb2+, Cu2+, Hg2+, Ag+, Fe2+, Co2+, Ni2+, Mn2+, Ca2+, Na+, Mg2+, and K+ was investigated in 1:1 (v/v) MeCN/H2O solutions. A strong chelation enhancement of quenching effect was observed on the fluorescent emission intensity of L2 as a consequence of the host−guest interaction with Hg2+ and the formation of a 1:2 metal-to-ligand complex. Density functional theory calculations confirmed the formation of a sandwich-type complex between L2 and Hg2+ as a favorable process. A matrix-assisted laser desorption/ionization (MALDI) time-of-flight mass spectrometry study using the four ligands as active MALDI probes was also performed. L1−L4 have also been explored as fluorescence chemosensors in microsamples using NANODROP technology." @default.
• W1992628850 created "2016-06-24" @default.
• W1992628850 creator A5027570897 @default.
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• W1992628850 creator A5072974132 @default.
• W1992628850 creator A5075711050 @default.
• W1992628850 creator A5089854809 @default.
• W1992628850 date "2010-08-17" @default.
• W1992628850 modified "2023-10-03" @default.
• W1992628850 title "Hg²⁺ Detection by New Anthracene Pendant-Arm Derivatives of Mixed N/S- and N/S/O-Donor Macrocycles: Fluorescence, Matrix-Assisted Laser Desorption/Ionization Time-of-Flight Mass Spectrometry and Density Functional Theory Studies" @default.
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• W1992628850 doi "https://doi.org/10.1021/ic1007439" @default.
• W1992628850 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20715769" @default.
• W1992628850 hasPublicationYear "2010" @default.

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