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- W1992632083 abstract "Die Reaktion von cp′TiCl3 mit LiN(SiMe3)2 · Et2O 1 führt zu den Verbindungen cp′TiCl2N(SiMe3)2 (cp′ = C5H5 2, C5H4SiMe3 3, C5H3(SiMe3)2 4, C5Me5 5) und cp′TiCl[N(SiMe3)2]2 (cp′ = C5H5 6). Verbindung 2 wurde durch eine Einkristall Röntgenstrukturanalyse charakterisiert. 2 kristallisiert in der Raumgruppe P21/n mit a = 1 660,9(7), b = 688,6(3), c = 1 739,1(8) pm und β = 117,18(3)°. New Complexes of Titanium with Bis(trimethylsilyl)amido Ligands The reaction of cp′TiCl3 with LiN(SiMe3)2 · Et2O 1 yield the compounds cp′TiCl2N(SiMe3)2 (cp′ = C5H5 2, C5H4SiMe3 3, C5H3(SiMe3)2 4, C5Me5 5) and cp′TiCl[N(SiMe3)2]2 (cp′ = C5H5 6). Compound 2 was characterized by an X-ray structural analysis with space group P21/n and unit cell dimensions of a = 1 660.9(7), b = 688.6(3), c = 1 739.1(8) pm and β = 117.18(3)°." @default.
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- W1992632083 date "1991-04-01" @default.
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- W1992632083 title "Neue Komplexe des Titans mit Bis(trimethylsilyl)amido-Liganden" @default.
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- W1992632083 doi "https://doi.org/10.1002/zaac.19915950104" @default.
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