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• W1992641182 abstract "ESR spectra were observed on tetrakis(cupferronato)uranium(IV) and tetrakis(neocupferronato)uranium(IV) at room temperature and 77 K with g-value of 4·27 and 4·50, respectively. In the solution of degassed tetrahydrofuran, the same signal was observed only at 77 K. Since these signals did not appear in the corresponding diamagnetic complexes with Th(IV), Ce(IV), Hf(IV), Zr(IV), and Ti(IV), the spectra were discussed from the point of the crystal field effect with the symmetry of D4d on 3H4 term of U(IV) with (5f)2 electronic configuration. On the other hand, ESR spectr having g-values of 2·003 ∼ 2·005 were also observed irrespectively to the kind of the central metal ion. As one of the possible causes of these signals, an unpaired electron produced by an NN bond fission in the ligand after the formation of the complex seems to be considered." @default.
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• W1992641182 date "1975-03-01" @default.
• W1992641182 modified "2023-10-17" @default.
• W1992641182 title "Electron spin resonance of uranium(IV) chelates with cupferron and neocupferron" @default.
• W1992641182 cites W1972150996 @default.
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• W1992641182 doi "https://doi.org/10.1016/0022-1902(75)80531-8" @default.
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