FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1992647105> ?p ?o ?g. }

• W1992647105 endingPage "668" @default.
• W1992647105 startingPage "651" @default.
• W1992647105 abstract "Optical roughness of a pyrolytic graphite electrode with basal (PGEb) and edge orientation (PGEe), a glassy carbon electrode (GCE), and the same electrodes modified with mercury (MFE) was studied by an optical diffractive element (DOE) based sensor. Electrochemical characterisation of these electrodes used was performed by cyclic voltammetry (CV) and capacitance measurements (C–E curves and electrochemical impedance spectroscopy, EIS). The kinetics of phase transients of adenosine adsorbed on PGEb, and GCE modified with mercury layer of different thicknesses (thickness was changed from 0.02 to 2 μm) was studied by chronoamperometry (j–t curves) and capacitance measurements (C–E curves). In acidic (pH 5) solution adenosine forms two different two-dimensional (2D) physisorbed condensed layers on the MFE. The first of these (region I) is located at more positive potential; the centre of this adlayer is situated around −0.4 V. The second 2D physisorbed film (region III) is formed at more negative potentials; the centre of the region III is around −1.3 V. The 2D condensed films (adlayer I and III) of adenosine still exist on the PGEb substrate modified by 0.02 μm thick mercury layer. Adlayers III and I of adenosine exist on the GCE modified with mercury layer down to 0.02 and 0.2 μm, respectively. The kinetics of phase transients of the adenosine films taking place by a potential jump from dilute adsorption region (state II and IV) to the 2D physisorbed film (region I and III) at the PGEb and GCE substrates modified with mercury (Hg–PGEb and Hg–GCE) were studied, respectively. During both of the phase transients of IV→III and II→III of adenosine a polynucleation and growth process on both the Hg–PGEb and Hg–GCE was detected. The phase transients of II→I are characterised by an exponential decay of the current without the current maximum (the adsorption process took place only). It was observed that the phase transients of IV→III are the fastest at the HMDE and gradually slow down on 2 μm Hg–GCE and 2 μm Hg–PGEb, respectively." @default.
• W1992647105 created "2016-06-24" @default.
• W1992647105 creator A5061445953 @default.
• W1992647105 date "2003-02-05" @default.
• W1992647105 modified "2023-10-16" @default.
• W1992647105 title "On the adsorption and kinetics of phase transients of adenosine at the different carbon electrodes modified with a mercury layer" @default.
• W1992647105 cites W1490916943 @default.
• W1992647105 cites W1522995334 @default.
• W1992647105 cites W1532038495 @default.
• W1992647105 cites W1552090312 @default.
• W1992647105 cites W1965122089 @default.
• W1992647105 cites W1965239507 @default.
• W1992647105 cites W1970544232 @default.
• W1992647105 cites W1975535547 @default.
• W1992647105 cites W1979468712 @default.
• W1992647105 cites W1995536832 @default.
• W1992647105 cites W1996196178 @default.
• W1992647105 cites W2001669386 @default.
• W1992647105 cites W2002016815 @default.
• W1992647105 cites W2002318697 @default.
• W1992647105 cites W2004624248 @default.
• W1992647105 cites W2005603113 @default.
• W1992647105 cites W2009480849 @default.
• W1992647105 cites W2010108522 @default.
• W1992647105 cites W2014823111 @default.
• W1992647105 cites W2016634010 @default.
• W1992647105 cites W2026454269 @default.
• W1992647105 cites W2026774976 @default.
• W1992647105 cites W2028650277 @default.
• W1992647105 cites W2029755808 @default.
• W1992647105 cites W2032074012 @default.
• W1992647105 cites W2036557798 @default.
• W1992647105 cites W2037951914 @default.
• W1992647105 cites W2043323097 @default.
• W1992647105 cites W2043523262 @default.
• W1992647105 cites W2044938986 @default.
• W1992647105 cites W2046179696 @default.
• W1992647105 cites W2048527952 @default.
• W1992647105 cites W2050027828 @default.
• W1992647105 cites W2060626758 @default.
• W1992647105 cites W2061438863 @default.
• W1992647105 cites W2066460068 @default.
• W1992647105 cites W2067302308 @default.
• W1992647105 cites W2069663461 @default.
• W1992647105 cites W2070008205 @default.
• W1992647105 cites W2071614339 @default.
• W1992647105 cites W2072402484 @default.
• W1992647105 cites W2073540943 @default.
• W1992647105 cites W2075061272 @default.
• W1992647105 cites W2075940627 @default.
• W1992647105 cites W2077423899 @default.
• W1992647105 cites W2081687237 @default.
• W1992647105 cites W2084740488 @default.
• W1992647105 cites W2088333566 @default.
• W1992647105 cites W2095411993 @default.
• W1992647105 cites W2119728241 @default.
• W1992647105 cites W2123145412 @default.
• W1992647105 cites W2138339058 @default.
• W1992647105 cites W2145884973 @default.
• W1992647105 cites W2146981257 @default.
• W1992647105 cites W319455403 @default.
• W1992647105 cites W3206074184 @default.
• W1992647105 cites W562022936 @default.
• W1992647105 cites W564296967 @default.
• W1992647105 cites W583375159 @default.
• W1992647105 cites W8897049 @default.
• W1992647105 cites W2014479986 @default.
• W1992647105 doi "https://doi.org/10.1016/s0013-4686(02)00735-1" @default.
• W1992647105 hasPublicationYear "2003" @default.
• W1992647105 type Work @default.
• W1992647105 sameAs 1992647105 @default.
• W1992647105 citedByCount "19" @default.
• W1992647105 countsByYear W19926471052012 @default.
• W1992647105 countsByYear W19926471052013 @default.
• W1992647105 countsByYear W19926471052014 @default.
• W1992647105 countsByYear W19926471052016 @default.
• W1992647105 countsByYear W19926471052019 @default.
• W1992647105 crossrefType "journal-article" @default.
• W1992647105 hasAuthorship W1992647105A5061445953 @default.
• W1992647105 hasConcept C113196181 @default.
• W1992647105 hasConcept C136774802 @default.
• W1992647105 hasConcept C147789679 @default.
• W1992647105 hasConcept C150394285 @default.
• W1992647105 hasConcept C17525397 @default.
• W1992647105 hasConcept C178790620 @default.
• W1992647105 hasConcept C185592680 @default.
• W1992647105 hasConcept C2776422427 @default.
• W1992647105 hasConcept C2777869211 @default.
• W1992647105 hasConcept C2778141235 @default.
• W1992647105 hasConcept C2779603750 @default.
• W1992647105 hasConcept C36759035 @default.
• W1992647105 hasConcept C52859227 @default.
• W1992647105 hasConcept C6775980 @default.
• W1992647105 hasConcept C7040849 @default.
• W1992647105 hasConceptScore W1992647105C113196181 @default.
• W1992647105 hasConceptScore W1992647105C136774802 @default.
• W1992647105 hasConceptScore W1992647105C147789679 @default.
• W1992647105 hasConceptScore W1992647105C150394285 @default.

• next