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- W1992648233 abstract "Cell free preparations from excised epidermis of pea leaves and whole leaf extracts catalyzed the decarboxylation of n-[9,10,11-3H]dotriacontanoic acid to alkanes in the presence of ascorbic acid and oxygen. The products were identified by radio gas-liquid chromatography as n-C31 alkane and n-C30 alkane suggesting that both direct decarboxylation and α-oxidation followed by decarboxylation occurred. Imidazole inhibited the formation of both n-C30 alkane and n-C31 alkane from n-C32 acid. Synthetic α-hydroxy C32 acid was converted to n-C31 alkane. Therefore, this hydroxy acid is suggested to be an intermediate in the conversion of C32 acid to C31 alkane. Alkane formation by the cell free preparation was also inhibited by parachloromercuribenzoate, dithioerythritol, ethylenediamine tetraacetate, and o-phenanthroline. The decarboxylase activity was located in the 100,000 xg supernatant." @default.
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- W1992648233 date "1974-12-01" @default.
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- W1992648233 title "Decarboxylation of long chain fatty acids to alkanes by cell free preparations of pea leaves (Pisum sativum)" @default.
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- W1992648233 doi "https://doi.org/10.1016/s0006-291x(74)80436-5" @default.
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