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- W1992671233 abstract "Abstract All intrinsic semi-conducting elements at absolute zero of temperature have their valence electrons occupying completely the valence band, the electrons being localized as co-valent spin pairs. At non-zero temperature, a fraction of these pairs gets broken, with the corresponding electrons thermally excited into the conduction band. The conduction electrons can be considered ‘non-localized’ and the process of spin decoupling, one of configurational entropy gain for the whole system. On considering the electronic wave function as mixed in character due to electrons ‘localized’ and ‘non-localized’, one can write it as a superposition of a metallic and a cevalent wave function. The resultant Hamiltonian permits one to calculate the configurational entropy of electrons in semiconducting elements and some semiconducting compounds. It is this contribution which is shown to be the reason of excess entropy of fusion of all semiconductor elements. The analysis elucidates some of the anomalous electronic behavior of semimetallic and semiconducting compounds." @default.
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- W1992671233 modified "2023-09-25" @default.
- W1992671233 title "Configurational entropy of electrons in semiconductors" @default.
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- W1992671233 doi "https://doi.org/10.1080/00337577008234962" @default.
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