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- W1992710080 abstract "Der Donor-Akzeptorkomplex P2O3Cl4 · 2 SbCl5 wird bei −20°C aus P2O3Cl4 und überschüssigem SbCl5 in Tetrachlorkohlenstoff hergestellt. Nach dem Schwingungsspektrum und nach den 121Sb-Mößbauer-Parametern sind die SbCl5-Moleküle an die terminalen O-Atome des P2O3Cl4 gebunden. Thermolyse des Addukts führt zu dem bereits früher beschriebenen Dichlorphosphat [SbCl4(O2PCl2)]2, dessen Kristallstruktur mit Hilfe von Röntgenbeugung ermittelt wurde. Die Verbindung kristallisiert monoklin in der Raumgruppe P21/c mit zwei dimeren Molekülen pro Elementarzelle (1843 unabhängige, beobachtete Reflexe, R = 4,0%). Die Gitterabmessungen sind a = 857, b = 1144, c = 1091 pm; β = 108,6°. In dem Molekül sind zwei SbCl4-Einheiten über die O-Atome der Dichlorophosphatgruppen zu einem zentrosymmetrischen Sb2O4P2-Achtring der Sesselkonformation verknüpft. On 121Sb-Mössbauer Effect. VIII. Vibrational Spectrum and 121Sb-Mössbauer Spectrum of P2O3Cl4 · 2 SbCl5. Crystal Structure of [SbCl4(O2PCl2)]2 The donor-acceptor complex P2O3Cl4 · 2 SbCl5 is prepared from P2O3Cl4 and excess SbCl5 in carbon tetrachloride at −20°C. According to the vibrational spectrum and the 121Sb-Mössbauer parameters the SbCl5 molecules are bonded to the terminal O atoms of P2O3Cl4. Thermolysis of the adduct yields the dichloro phosphate [SbCl4(O2PCl2)]2 which has been discussed earlier. The crystal structure of the dimer was determined by means of X-ray diffraction; it crystallizes monoclinic in the space group P21/c with two dimeric molecules per unit cell (1843 independent, observed reflexions, R = 4.0%). The cell dimensions are a = 857 pm, b = 1144 pm, c = 1091 pm; β = 108.6°. In the molecule two SbCl4 units are linked by the O atoms of the dichlorophosphate groups to form a centrosymmetric eightmembered ring with chair conformation." @default.
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- W1992710080 date "1985-05-01" @default.
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- W1992710080 title "Beitr�ge zum121Sb-M��bauer-Effekt. VIII. Schwingungsspektrum und121Sb-M��bauer-Spektrum von P2O3Cl4 � 2 SbCl5 Die. Kristallstruktur von [SbCl4(O2PCl2)]2" @default.
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- W1992710080 doi "https://doi.org/10.1002/zaac.19855240509" @default.
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