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• W1992725595 startingPage "16780" @default.
• W1992725595 abstract "UV laser excitation of cryogenic solids doped with cyanoethyne, HC3N, led to an in situ creation of longer carbon–nitrogen chains, namely HC5N, C4N2, and C6N2, heralded by their strong visible luminescence. HC5N and C4N2 molecules can form, most probably, within HC3N aggregates linked by hydrogen bonds, while the reaction occurring between two isolated, photochemically created C3N radicals yields C6N2. This latter species, dicyanobutadiyne, is easily detected in Ar, Kr, N2, as well as in parahydrogen solids. The C6N2 phosphorescence is identified here for the first time. The reported carbon chain coupling reactions in rigid environments are of interest for astrochemistry of interstellar ices." @default.
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• W1992725595 date "2011-01-01" @default.
• W1992725595 modified "2023-10-17" @default.
• W1992725595 title "UV-induced growth of cyanopolyyne chains in cryogenic solids" @default.
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• W1992725595 doi "https://doi.org/10.1039/c1cp21326a" @default.
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