Matches in SemOpenAlex for { <https://semopenalex.org/work/W1992725616> ?p ?o ?g. }
Showing items 1 to 84 of
84
with 100 items per page.
- W1992725616 abstract "Abstract The kinetics of the oxidation of uranium (IV) by thallium (III) in the presence of tartaric acid was investigated in aqueous perchloric acid solutions. Increases in initial rate with increasing tartaric acid concentrations were observed, along with departure from the second-order rate law. The orders with respect to uranium (IV), thallium (III), tartaric acid, and hydrogen ion were found to be 0·93, 0·05, 0·37 and −0·91, respectively. Thallium (III) in the presence of tartaric acid was shown to be stable by polarography, yet in kinetics experiments with Tl(III) in excess over uranium (IV), the reaction stopped because the Tl(III) was consumed. The oxidation of U(IV) by oxygen of the air is catalysed by the presence of tartaric acid, but this reaction is negligibly slow compared to the U(IV)Tl(III)-tartaric acid reactions. The presence of U(VI), and Tl(I) were shown to have no effect on the reaction kinetics. A mechanistic interpretation has been developed to account for the observed results." @default.
- W1992725616 created "2016-06-24" @default.
- W1992725616 creator A5003364577 @default.
- W1992725616 creator A5027647148 @default.
- W1992725616 creator A5050309629 @default.
- W1992725616 date "1965-10-01" @default.
- W1992725616 modified "2023-09-27" @default.
- W1992725616 title "The effect of tartaric acid on the kinetics of the oxidation of uranium (IV) by thallium (III) in aqueous perchloric acid" @default.
- W1992725616 cites W1977244463 @default.
- W1992725616 cites W1995332675 @default.
- W1992725616 cites W2001530369 @default.
- W1992725616 cites W2018041174 @default.
- W1992725616 cites W2021648129 @default.
- W1992725616 cites W2036116888 @default.
- W1992725616 cites W2043279237 @default.
- W1992725616 cites W2318750682 @default.
- W1992725616 doi "https://doi.org/10.1016/0022-1902(65)80236-6" @default.
- W1992725616 hasPublicationYear "1965" @default.
- W1992725616 type Work @default.
- W1992725616 sameAs 1992725616 @default.
- W1992725616 citedByCount "3" @default.
- W1992725616 crossrefType "journal-article" @default.
- W1992725616 hasAuthorship W1992725616A5003364577 @default.
- W1992725616 hasAuthorship W1992725616A5027647148 @default.
- W1992725616 hasAuthorship W1992725616A5050309629 @default.
- W1992725616 hasConcept C121332964 @default.
- W1992725616 hasConcept C13965031 @default.
- W1992725616 hasConcept C148898269 @default.
- W1992725616 hasConcept C178790620 @default.
- W1992725616 hasConcept C179104552 @default.
- W1992725616 hasConcept C184651966 @default.
- W1992725616 hasConcept C185592680 @default.
- W1992725616 hasConcept C191897082 @default.
- W1992725616 hasConcept C192562407 @default.
- W1992725616 hasConcept C2778161354 @default.
- W1992725616 hasConcept C2779032678 @default.
- W1992725616 hasConcept C2780048820 @default.
- W1992725616 hasConcept C36663273 @default.
- W1992725616 hasConcept C555451288 @default.
- W1992725616 hasConcept C559099789 @default.
- W1992725616 hasConcept C62520636 @default.
- W1992725616 hasConceptScore W1992725616C121332964 @default.
- W1992725616 hasConceptScore W1992725616C13965031 @default.
- W1992725616 hasConceptScore W1992725616C148898269 @default.
- W1992725616 hasConceptScore W1992725616C178790620 @default.
- W1992725616 hasConceptScore W1992725616C179104552 @default.
- W1992725616 hasConceptScore W1992725616C184651966 @default.
- W1992725616 hasConceptScore W1992725616C185592680 @default.
- W1992725616 hasConceptScore W1992725616C191897082 @default.
- W1992725616 hasConceptScore W1992725616C192562407 @default.
- W1992725616 hasConceptScore W1992725616C2778161354 @default.
- W1992725616 hasConceptScore W1992725616C2779032678 @default.
- W1992725616 hasConceptScore W1992725616C2780048820 @default.
- W1992725616 hasConceptScore W1992725616C36663273 @default.
- W1992725616 hasConceptScore W1992725616C555451288 @default.
- W1992725616 hasConceptScore W1992725616C559099789 @default.
- W1992725616 hasConceptScore W1992725616C62520636 @default.
- W1992725616 hasLocation W19927256161 @default.
- W1992725616 hasOpenAccess W1992725616 @default.
- W1992725616 hasPrimaryLocation W19927256161 @default.
- W1992725616 hasRelatedWork W131495220 @default.
- W1992725616 hasRelatedWork W1559912433 @default.
- W1992725616 hasRelatedWork W1965084235 @default.
- W1992725616 hasRelatedWork W1979366805 @default.
- W1992725616 hasRelatedWork W1990973749 @default.
- W1992725616 hasRelatedWork W1998984770 @default.
- W1992725616 hasRelatedWork W2004132338 @default.
- W1992725616 hasRelatedWork W2008188684 @default.
- W1992725616 hasRelatedWork W2011931113 @default.
- W1992725616 hasRelatedWork W2017840220 @default.
- W1992725616 hasRelatedWork W2027475236 @default.
- W1992725616 hasRelatedWork W2042120244 @default.
- W1992725616 hasRelatedWork W2048978365 @default.
- W1992725616 hasRelatedWork W2086746200 @default.
- W1992725616 hasRelatedWork W2094720439 @default.
- W1992725616 hasRelatedWork W2317763592 @default.
- W1992725616 hasRelatedWork W282539489 @default.
- W1992725616 hasRelatedWork W3095774103 @default.
- W1992725616 hasRelatedWork W309922057 @default.
- W1992725616 hasRelatedWork W96111574 @default.
- W1992725616 isParatext "false" @default.
- W1992725616 isRetracted "false" @default.
- W1992725616 magId "1992725616" @default.
- W1992725616 workType "article" @default.