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- W1992744741 abstract "In situ spectroelectrochemical measurements with external reflection FT-IR are performed at different stages of polymerization of 0.05, 0.1 and 0.8 M biphenyl in 0.1 M TBABF4 in acetonitrile. The biphenyl concentration is not found to have any effect on the structure of the polymer formed. Formation of oligomers and the ratio of ortho/para-substituted polymer chains during film growth are studied. The first coupling of dimers to oligomers is found to take place in the vicinity of the electrode surface and at a later stage of polymerization the oligomers start to form polymer film on the electrode. A mixed para and ortho coupling resulting in crosslinking between chains is observed already at the early stage of polymerization. However, when a lower current density is used a more ordered polymer structure is obtained. A breakdown of the polymer film due to overoxidation can be seen when the potential is increased to 2.0 V." @default.
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- W1992744741 date "1994-01-01" @default.
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- W1992744741 title "Spectroelectrochemical study of polyphenylene by in situ external reflection FT-IR spectroscopy I. Polymerization of biphenyl" @default.
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- W1992744741 doi "https://doi.org/10.1016/0379-6779(94)90303-4" @default.
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