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• W1992757684 abstract "The mechanism for the formation of hexamethylenetetraamine predicts the formation of aminomethanol from the addition of ammonia to formaldehyde. This molecule subsequently undergoes unimolecular decomposition to form methanimine and water. Aminomethanol is the predicted precursor to interstellar glycine, and is therefore of great interest for laboratory spectroscopic study, which would serve as the basis for observational searches. The height of the water loss barrier is therefore useful in the determination of an appropriate experimental approach for spectroscopic characterization of aminomethanol. We have determined the height of this barrier to be 55 kcalmol at ambient temperatures. In addition, we have determined the infinite-pressure Rice-Ramsperger-Kassel-Marcus unimolecular decomposition rate to be <10(-25) s(-1) at 300 K, indicating gas-phase kinetic stability for typical laboratory and hot core temperatures. Therefore, spectroscopic characterization of and observational searches for this molecule should be straightforward provided an efficient formation mechanism can be found." @default.
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• W1992757684 date "2005-07-15" @default.
• W1992757684 modified "2023-09-25" @default.
• W1992757684 title "Aminomethanol water elimination: Theoretical examination" @default.
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• W1992757684 doi "https://doi.org/10.1063/1.1935510" @default.
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