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- W1992783233 abstract "Developing an efficient redox material is crucial for thermochemical cycles that produce solar fuels (e.g., H2 and CO), enabling a sustainable energy supply. In this study, the effects of varying the rare-earth content y in Ce0.85-yZr0.15REyO2–0.5y with RE = Y, La, Sm and Gd on the fuel productivity and long-term stability were investigated. Compared to the none-RE-doped reference material, Ce0.85Zr0.15O2, none of the compositions exhibits higher performances. However, long-term cycling of more than 80 cycles reveals enhanced performance due to rare-earth doping. Ce0.85Zr0.15O2 suffers from linear degradation of the yields and of the CO:O2 ratio r, which is attributed to declining oxidation kinetics, whereas for instance Ce0.82Zr0.15Sm0.03O1.99 features stable yields and kinetics. The suggested rationale behind is found in a vacancy-depleted region that occurs in the grains of Ce0.85Zr0.15O2. While cycling, the specific surface decreases and the impact of these regions on the reaction rate increases which..." @default.
- W1992783233 created "2016-06-24" @default.
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- W1992783233 date "2015-03-24" @default.
- W1992783233 modified "2023-09-25" @default.
- W1992783233 title "Ceria Doped with Zirconium and Lanthanide Oxides to Enhance Solar Thermochemical Production of Fuels" @default.
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- W1992783233 doi "https://doi.org/10.1021/jp508959y" @default.
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