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- W1992807268 abstract "The synthesis and characterization of two deepened cavitand hosts with introverted functionalityfunctional groups directed into the cavityis described. Two functions can be introverted, alcohol and aldehyde, and they show the formation of hemiacetals and hemiketals on binding small guests with complementary functional groups. The structures of the bound hemiacetals are determined by 1D and 2D NMR studies. The arrangements of the guests in the cavitands enhance the equilibrium constants of carbonyl additions, K/Kctrl, between 13- and 105-fold, compared to their counterparts in solution. The stabilization of the addition products is due to the prior complexation of the guests and the organized solvation provided to the tetrahedral intermediates by a network of secondary amides at the cavitand rim." @default.
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- W1992807268 date "2007-11-16" @default.
- W1992807268 modified "2023-10-17" @default.
- W1992807268 title "Cavitands with Introverted Functionality Stabilize Tetrahedral Intermediates" @default.
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- W1992807268 doi "https://doi.org/10.1021/ja0756366" @default.
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