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- W1992812217 abstract "Kinetic studies of the reaction of substituted dihalogenoepoxybutanes with ketones catalysed by Lewis acids reveal its multicentre character. Interaction of an oxiran with a Lewis acid already complexed with a ketone (or other ligand) probably results in the formation of a donor–acceptor Lewis acid–oxiran complex. The transformation of this complex into the activated form involves attack by a ketone molecule from the salvation shell of the complex according to a ‘push–pull’ mechanism. This step can lead to isomerisation of the oxiran as well as to the formation of a dioxolan. The formation of the Lewis acid–oxiran complex can in some cases be the rate-limiting process." @default.
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- W1992812217 date "1977-01-01" @default.
- W1992812217 modified "2023-09-26" @default.
- W1992812217 title "Mechanism of the reaction of dihalogeno-oxirans with ketones catalysed by some Lewis acids" @default.
- W1992812217 doi "https://doi.org/10.1039/p29770001526" @default.
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