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- W1992831488 abstract "An efficient approach to the syntheses of amphiphilic rod−coil diblock and coil−rod−coil triblock copolymers was developed. Each diblock copolymer consists of a perfectly monodispersed oligo(phenylene vinylene) covalently bonded to a poly(ethylene glycol) block with a very low polydispersity (<1.05). The structure and basic physical properties of these copolymers were characterized by various spectroscopic techniques such as NMR, MALDI-TOF, GPC, DSC, UV/vis, and the fluorescence study. These diblock copolymers were shown to possess remarkable self-assembling abilities, and long cylindrical micelles (>1 μm) were formed. TEM, SANS, and AFM studies showed that the core of the micelles has a diameter of ∼8−10 nm and was composed of an OPV block. TEM and SANS studies revealed that these OPV-PEG micelles have a cylindrical OPV core surrounded by a PEG corona. Cryo-TEM and SANS studies indicate that fibers were formed even in very dilute THF/H2O solutions. Since the conjugated OPV blocks exhibit liquid crystallinity and electric and optical properties, these micelles are interesting for studying the electroactive effect in a nanometer scale." @default.
- W1992831488 created "2016-06-24" @default.
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- W1992831488 date "2000-07-06" @default.
- W1992831488 modified "2023-10-11" @default.
- W1992831488 title "Syntheses of Amphiphilic Diblock Copolymers Containing a Conjugated Block and Their Self-Assembling Properties" @default.
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- W1992831488 doi "https://doi.org/10.1021/ja0010812" @default.
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