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• W1992835596 abstract "The adsorption of carbonate and bicarbonate ions on Pt(111) and Pt(110) has been studied using Fourier transform IR spectroscopy. At Pt(111) the spectral analysis provides evidence for the adsorption of one- and two-fold coordinated carbonate ions depending on the electrode potential. At Pt(110) only two-fold coordinated carbonate was detected. Bicarbonate ions are oriented at the Pt(111)|electrolyte interface, probably forming hydrogen bonds with adsorbed water. The potential dependence of the band centers is discussed in terms of the proposed adsorption model." @default.
• W1992835596 created "2016-06-24" @default.
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• W1992835596 date "1995-02-01" @default.
• W1992835596 modified "2023-10-18" @default.
• W1992835596 title "Vibrational spectroscopy of carbonate adsorbed on Pt(111) and Pt(110) single-crystal electrodes" @default.
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• W1992835596 doi "https://doi.org/10.1016/0022-0728(94)03708-b" @default.
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