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- W1992852877 abstract "Abstract Thermolysis of p -tolyl benzenesulfonate and p -tolyl p -toluenesulfonate in boiling tetralin for 5 h yielded SO 2 , together with the corresponding arene, biaryl, arenesulfonic acid, 2-and/or 4-hydroxybiphenyl derivatives, phenols, p -cresol, diaryl sulfone, diaryl sulfide, o -tolylphenol, and p -tolylphenol. Similar results were obtained on thermolysis of β-naphthyl benzenesulfonate; products included naphthalene, 2-phenylnaphthalene, β-naphthol, 2,2′-dinaphthyl, 2,2′-dinaphthol, 2-naphthalenesulfonic acid, and phenyl 1-naphthylsulfone. Photolysis of these arenesulfonate aryl esters afforded the biaryl, diaryl esters, phenols and 2-naphthol. A free radical mechanism is suggested to account for the observed results." @default.
- W1992852877 created "2016-06-24" @default.
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- W1992852877 date "1994-06-01" @default.
- W1992852877 modified "2023-09-28" @default.
- W1992852877 title "Molecular rearrangements of sulfur compounds. Thermolysis and photolysis of arenesulfonate aryl esters" @default.
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- W1992852877 doi "https://doi.org/10.1016/0165-2370(93)00787-n" @default.
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