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- W1992862103 abstract "The chance to prepare sterically and inductively stabilized arsa- and phosphaalkenes of the type PhE=C(CF3)2 (E = As, P) by reacting phenyl-bis(trimethylsilyl)-arsane (1) and -phosphane (5), respectively, with hexafluoroacetone (HFA) was investigated. The insertion of the carbonyl function in one of the Si–E bonds was found to occur at temperatures between −78 and 20 °C. The elimination of hexamethyldisiloxane, which in case of acylamides and ketones spontaneously follows the insertion and in case of RE(SiMe3)–CR′2(OSiMe3) at least can be initiated by solid sodium hydroxide as catalyst, turned out to be impossible for the primary products PhE(SiMe3)–C(CF3)2-OSiMe3 [E = As (2), P (6)]. 2 and 6 were characterized by analytical (C, H) and spectroscopic methods (IR, NMR, MS)." @default.
- W1992862103 created "2016-06-24" @default.
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- W1992862103 date "2005-09-01" @default.
- W1992862103 modified "2023-09-27" @default.
- W1992862103 title "Reactive E=C(p-p)π-Systems. 56 [1] Attempted Preparation of PhE=C(CF3)2 by Reactions of Hexafluoroacetone with PhE(SiMe3)2 (E = As, P)" @default.
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- W1992862103 doi "https://doi.org/10.1002/zaac.200500237" @default.
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