FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1992873072> ?p ?o ?g. }

• W1992873072 endingPage "229" @default.
• W1992873072 startingPage "220" @default.
• W1992873072 abstract "The influence of Al cations on the electrochemical carboxylation of acenaphthylene (1), benzophenone (2), 6-methoxy-2-acetonaphthone (3), and benzyl chloride (4) has been investigated in dimethylformamide at a glassy carbon cathode. The Al3+ ions were either added at the beginning of the experiment or were released from the anode during electrocarboxylation. It has been found that when Al cations are added to the reaction medium, they strongly influence the reduction process, in most cases leading to a complete change of the mechanism. For example, in the case of 1, the radical anion (1−) formed upon 1e− reduction rapidly reacts with Al3+ to give an Al(III) adduct, which is further reduced either at the electrode or in solution by disproportionation. The rate constant of the adduct formation is ca. 3 orders of magnitude larger than that of the carboxylation reaction between 1− and CO2. By contrast, when Al3+ ions are supplied to the reaction medium in concomitance with carboxylate formation, hence by oxidation of the anode during electrocarboxylation, they show no effect on the cathodic process. This has been confirmed both by voltammetric investigations and preparative scale experiments. It thus appears that whereas free Al3+ ions strongly influence the reduction process, the metal cations produced by the consumable anode in undivided cells are intercepted and complexed by the carboxylated products before they can reach the cathode. Therefore, the cathodic process occurs in a medium without free Al3+ ions." @default.
• W1992873072 created "2016-06-24" @default.
• W1992873072 creator A5045367455 @default.
• W1992873072 creator A5051563095 @default.
• W1992873072 creator A5068671007 @default.
• W1992873072 creator A5073506714 @default.
• W1992873072 date "2005-11-01" @default.
• W1992873072 modified "2023-09-28" @default.
• W1992873072 title "The influence of aluminium cations on electrocarboxylation processes in undivided cells with Al sacrificial anodes" @default.
• W1992873072 cites W1538944932 @default.
• W1992873072 cites W1577579915 @default.
• W1992873072 cites W1580949956 @default.
• W1992873072 cites W1968050429 @default.
• W1992873072 cites W1970494705 @default.
• W1992873072 cites W1970696490 @default.
• W1992873072 cites W1972819582 @default.
• W1992873072 cites W1976953864 @default.
• W1992873072 cites W1988913009 @default.
• W1992873072 cites W1994618808 @default.
• W1992873072 cites W2000508963 @default.
• W1992873072 cites W2001918099 @default.
• W1992873072 cites W2005053866 @default.
• W1992873072 cites W2005592971 @default.
• W1992873072 cites W2020951664 @default.
• W1992873072 cites W2021231518 @default.
• W1992873072 cites W2025654600 @default.
• W1992873072 cites W2026114792 @default.
• W1992873072 cites W2026361700 @default.
• W1992873072 cites W2050606901 @default.
• W1992873072 cites W2052494037 @default.
• W1992873072 cites W2068590794 @default.
• W1992873072 cites W2069823896 @default.
• W1992873072 cites W2070028987 @default.
• W1992873072 cites W2072009217 @default.
• W1992873072 cites W2072506207 @default.
• W1992873072 cites W2079704561 @default.
• W1992873072 cites W2080870150 @default.
• W1992873072 cites W2085228185 @default.
• W1992873072 cites W2327667910 @default.
• W1992873072 cites W2950567379 @default.
• W1992873072 cites W2951723814 @default.
• W1992873072 cites W2952575596 @default.
• W1992873072 doi "https://doi.org/10.1016/j.jelechem.2005.08.012" @default.
• W1992873072 hasPublicationYear "2005" @default.
• W1992873072 type Work @default.
• W1992873072 sameAs 1992873072 @default.
• W1992873072 citedByCount "23" @default.
• W1992873072 countsByYear W19928730722013 @default.
• W1992873072 countsByYear W19928730722014 @default.
• W1992873072 countsByYear W19928730722016 @default.
• W1992873072 countsByYear W19928730722021 @default.
• W1992873072 countsByYear W19928730722022 @default.
• W1992873072 countsByYear W19928730722023 @default.
• W1992873072 crossrefType "journal-article" @default.
• W1992873072 hasAuthorship W1992873072A5045367455 @default.
• W1992873072 hasAuthorship W1992873072A5051563095 @default.
• W1992873072 hasAuthorship W1992873072A5068671007 @default.
• W1992873072 hasAuthorship W1992873072A5073506714 @default.
• W1992873072 hasConcept C108204754 @default.
• W1992873072 hasConcept C147789679 @default.
• W1992873072 hasConcept C161790260 @default.
• W1992873072 hasConcept C17365422 @default.
• W1992873072 hasConcept C17525397 @default.
• W1992873072 hasConcept C178790620 @default.
• W1992873072 hasConcept C179104552 @default.
• W1992873072 hasConcept C185592680 @default.
• W1992873072 hasConcept C24428623 @default.
• W1992873072 hasConcept C2777712214 @default.
• W1992873072 hasConcept C2780471494 @default.
• W1992873072 hasConcept C49110097 @default.
• W1992873072 hasConcept C52859227 @default.
• W1992873072 hasConcept C89395315 @default.
• W1992873072 hasConceptScore W1992873072C108204754 @default.
• W1992873072 hasConceptScore W1992873072C147789679 @default.
• W1992873072 hasConceptScore W1992873072C161790260 @default.
• W1992873072 hasConceptScore W1992873072C17365422 @default.
• W1992873072 hasConceptScore W1992873072C17525397 @default.
• W1992873072 hasConceptScore W1992873072C178790620 @default.
• W1992873072 hasConceptScore W1992873072C179104552 @default.
• W1992873072 hasConceptScore W1992873072C185592680 @default.
• W1992873072 hasConceptScore W1992873072C24428623 @default.
• W1992873072 hasConceptScore W1992873072C2777712214 @default.
• W1992873072 hasConceptScore W1992873072C2780471494 @default.
• W1992873072 hasConceptScore W1992873072C49110097 @default.
• W1992873072 hasConceptScore W1992873072C52859227 @default.
• W1992873072 hasConceptScore W1992873072C89395315 @default.
• W1992873072 hasIssue "2" @default.
• W1992873072 hasLocation W19928730721 @default.
• W1992873072 hasOpenAccess W1992873072 @default.
• W1992873072 hasPrimaryLocation W19928730721 @default.
• W1992873072 hasRelatedWork W1969596921 @default.
• W1992873072 hasRelatedWork W1971736301 @default.
• W1992873072 hasRelatedWork W1976929250 @default.
• W1992873072 hasRelatedWork W1982495113 @default.
• W1992873072 hasRelatedWork W2087961062 @default.
• W1992873072 hasRelatedWork W2332636940 @default.
• W1992873072 hasRelatedWork W2387133619 @default.
• W1992873072 hasRelatedWork W2517086061 @default.

• next