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- W1992875008 abstract "Abstract This paper describes the synthesis and physical properties of a chiral bent-core liquid crystal containing the chiral non-aromatic central ring system 1,5-anhydro-2-desoxy-D-arabino-hexitol. The preparation involved a stepwise construction of the mesogenic side chains via a selective diesterification of glucal at positions three and six with 4-O-acetylbenzoyl chloride followed by selective deacetylation. Repeated esterification of the aromatic hydroxy group with a substituted benzoic acid and hydrogenation of the double bond resulted in the desired product. To our knowledge, this is the first banana shaped liquid crystal synthesized containing a sugar derivative as a chiral core. Investigation of the mesogenic properties and electro-optic experiments showed traditional calamitic phases along with banana phases." @default.
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- W1992875008 date "2004-02-01" @default.
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- W1992875008 title "Chiral banana liquid crystals derived from sugars" @default.
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- W1992875008 doi "https://doi.org/10.1080/02678290310001639616" @default.
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