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- W1992891170 abstract "The behavior of the kinetic coefficients of binary gaseous mixtures has been studied in a vicinity of the gas-liquid critical line. It is shown experimentally by the diffusion equalization of concentration that the mutual diffusion coefficient D depends on the reduced temperature $ensuremath{tau}[ensuremath{tau}=(Tensuremath{-}{T}_{c}{)/T}_{c},$ where ${T}_{c}$ is the critical temperature] as a power function with exponent $ensuremath{gamma}ensuremath{sim}1.2$ up to $ensuremath{tau}ensuremath{sim}{10}^{ensuremath{-}3}--{10}^{ensuremath{-}4}$ at the approach to the critical point. The dependence $Densuremath{sim}{ensuremath{tau}}^{0.6}$ predicted by the scaling theory should be observed in closest proximity of the critical point. It is shown that the diffusion equalization of the isotope concentration does not have any peculiarity near the critical point. Equations of state are proposed for both pure substance and binary mixtures, based on up-to-date theories. They may be used to calculate the required thermodynamic derivatives for describing the temperature dependences of kinetic coefficients. The crossover temperatures have been determined. The experiments performed are in good agreement with our theoretical calculations." @default.
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- W1992891170 date "1999-03-01" @default.
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- W1992891170 title "Critical behavior of binary gaseous mixtures" @default.
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- W1992891170 doi "https://doi.org/10.1103/physreve.59.2927" @default.
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