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- W1992912235 abstract "The sharp and thermoreversible morphological transitions of poly(2-ethoxyethyl vinyl ether-b-2-hydroxyethyl vinyl ether) (poly(EOVE-b-HOVE)) in aqueous solutions have been investigated by means of small-angle neutron scattering. The poly(EOVE-b-HOVE), synthesized by living cationic polymerization, had the number-average degree of polymerizations of the constituent blocks of 200 and 400, respectively, and a polydispersity index of 1.07. The poly(EOVE-b-HOVE) underwent a disorder−order transition around 17−21 °C, depending on the polymer concentration. This is a micellization with a poly(EOVE) core of ca. 20 nm in radius and a poly(HOVE) corona. When the polymer concentration was high enough, e.g., 17 wt %, a macrolattice formation with body-centered cubic symmetry was also observed. This transition took place in a narrow temperature window of less than a degree centigrade. The origin of this sharp transition was found to be a dissociation of hydrophobically associated structure, such as an iceberg structur..." @default.
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- W1992912235 date "2002-09-12" @default.
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- W1992912235 title "Heat-Induced Self-Assembling of Thermosensitive Block Copolymer. 1. Small-Angle Neutron Scattering Study" @default.
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- W1992912235 doi "https://doi.org/10.1021/ma020480+" @default.
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