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- W1992912588 abstract "The decarboxylation–hydrogenolysis of prop-2-ynylic cyclic carbonates which have an internal acetylenic bond with ammonium formate in the presence of a catalytic amount of [Pd(acac)2] and Bun3P afforded (Z)-homoallylic alcohols or homoprop-2-ynylic alcohols depending on the reaction conditions, however, hydrogenolysis of terminal prop-2-ynylic cyclic carbonates gave homoallylic alcohols; using (Z)-homoallylic alcohol 2b as a chiral synthon, the male sex pheromone of the pyralid moth Aphomia gularis has been synthesized." @default.
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- W1992912588 date "1994-01-01" @default.
- W1992912588 modified "2023-09-26" @default.
- W1992912588 title "Synthesis of (Z)-homoallylic alcohols and homoprop-2-ynylic alcohols via palladium-catalysed hydrogenolysis of prop-2-ynylic cyclic carbonates" @default.
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- W1992912588 doi "https://doi.org/10.1039/p19940000237" @default.
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