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• W1992934485 abstract "Calibration of the intensity ratios for the fragment ions C7H7+ and C7H8+. formed by collision-induced dissociations, in terms of the increase in internal energy of the C10H14+. (butylbenzene) precursor ion, has been achieved in photodissociation experiments or by using charge-exchange ionization. The results of the various calibration experiments show large discrepancies between one another. The nature of these discrepancies is investigated. It is shown that a major contributing factor is the internal energy content of the C10H14+. precursor ions prior to excitation. Another important factor is the efficiency of detection of the fragment ions. Also, such calibrations of increases in internal energy should be applied only to results of collision-induced dissociations of ions which were prepared in the same way as for the calibration experiment, and which were studied in an identical apparatus." @default.
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• W1992934485 date "1985-07-01" @default.
• W1992934485 modified "2023-09-26" @default.
• W1992934485 title "Calibration of energy deposition in collision-induced dissociations of the butylbenzene molecular ion" @default.
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• W1992934485 doi "https://doi.org/10.1016/0168-1176(85)83008-1" @default.
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