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- W1992936196 abstract "The ligand L1 (N1,N3-di[2-di(2-pyridylmethyl)aminoethyl]N1,N3-dimethyl-1,3-propandiamine) bridges two tripodal units of the amine ligand Me2uns-penp (N1,N1-dimethyl-N2,N2-di(2-pyridylmethyl)-1,2-ethandiamine) with a propyl group. The ligand L1, the dinuclear copper(I) complex [Cu2(L1)](BPh4)2 and the dinuclear copper(II) complexes [Cu2Cl2(L1)](ClO4)2, and Cu2Cl2(L1)]Cl2 have been synthesized and structurally characterized. The copper(I) complex reacts reversibly with dioxygen at low temperatures and forms a peroxido complex that is thermally more stable than the related peroxido complex formed from two mononuclear copper(I) complexes of the ligand Me2uns-penp." @default.
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- W1992936196 date "2010-06-25" @default.
- W1992936196 modified "2023-09-26" @default.
- W1992936196 title "Stabilization of a copper peroxido complex with a new binucleating ligand" @default.
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- W1992936196 doi "https://doi.org/10.1080/00958972.2010.490876" @default.
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