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- W1993008730 abstract "Solid-state NMR spectroscopy of half-integer quadrupolar nuclides has received a lot of interest recently with the advent of new methodologies and higher magnetic fields. We present here the extension of our previous low temperature method to an 18.8 T system. This new probe entailed a total redesign including a cross coil and variable capacitors that are operational at cryogenic temperatures. The limitations to sensitivity are also discussed; including a new diode network, the utilization of a cryogenic band pass filter, and the consequences of the RF profiles of the coil. Further, details of the spectroscopy of quadrupolar nuclei in a protein are discussed, such as the observation of the outer transitions and how to distinguish them from the desired ±1/2 transition." @default.
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- W1993008730 date "2004-05-01" @default.
- W1993008730 modified "2023-10-10" @default.
- W1993008730 title "Low temperature solid-state NMR experiments of half-integer quadrupolar nuclides: caveats and data analysis" @default.
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- W1993008730 doi "https://doi.org/10.1016/j.jmr.2004.01.008" @default.
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