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- W1993014055 abstract "An effective asymmetric sulfa-Michael addition of various S-nucleophiles to a range of α,β-disubstituted nitroalkenes with bifunctional organocatalyst has been developed. The expected adducts could be obtained in high yields with reasonable diastereo- and enantioselectivities. This process provides an easy access to synthetically useful chiral 1,2-aminothiol derivatives bearing two vicinal stereocenters. Importantly, current work represents the first example about the catalytic asymmetric Michael addition of diverse S-nucleophiles except thioacetic acid to less reactive α,β-disubstituted nitroalkenes." @default.
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- W1993014055 date "2013-07-01" @default.
- W1993014055 modified "2023-10-18" @default.
- W1993014055 title "Organocatalytic diastereo- and enantioselective sulfa-Michael addition to α,β-disubstituted nitroalkenes" @default.
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- W1993014055 doi "https://doi.org/10.1016/j.tet.2013.04.125" @default.
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