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• W1993045387 abstract "In this work, we study the molar mass dependence of the thermodiffusion of polyethylene oxide at different temperatures in ethanol, water/ethanol mixture (cwater = 0.7), and water in a molar mass range up to Mw = 180 000 g/mol. Due to the low solubility of polyethylene oxide oligomers in ethanol the measurements are limited up to Mw = 2200 g/mol. The specific water/ethanol concentration 0.7 has been chosen, because at this weight fraction the thermal diffusion coefficient, DT, of water/ethanol vanishes so that the system can be treated as a pseudo binary mixture. The addition of ethanol will degrade the solvent quality, so that we expect a change of the interaction energies between polymer and solvent. The analysis of the experimental data within a theoretical model shows the need of a refined model, which takes specific interactions into account." @default.
• W1993045387 created "2016-06-24" @default.
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• W1993045387 date "2014-08-12" @default.
• W1993045387 modified "2023-10-18" @default.
• W1993045387 title "Molar mass and temperature dependence of the thermodiffusion of polyethylene oxide in water/ethanol mixtures" @default.
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• W1993045387 doi "https://doi.org/10.1063/1.4891720" @default.
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