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- W1993109935 abstract "Abstract— The photochemistry and photophysics of bis-(2-(9-anthryl)ethyl glutarate 2 and 2-(9-anthryl) ethyl pivalate 3 have been examined as monomeric models for poly-2-(9-anthryl)ethyl methacrylate 1. The absorption and excitation spectra of 2 show no ground state interaction, but appreciable monomer (51%) and excimer (49%) emission. Delayed monomer and excimer fluorescence are also observed in fluid solution at room temperature. Photolysis of 2 at low temperature produces a photoproduct (44% yield) which is unstable at room temperature and presumably is the head-to-head (H-H) dimer. Steady state irradiation of 2 at room temperature (Λ 350 nm) cleanly produces a head-to-tail (H-T) dimer (6) derived from the singlet state and an additional unidentified adduct (7). The product distribution is concentration dependent, with 6 predominating at high concentrations (> 10−3M). The fluorescence spectra of the broken dimers derived from 6 and 7 indicate that substantial ir overlap exists in the transition state leading to each product." @default.
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- W1993109935 date "1990-02-01" @default.
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- W1993109935 title "PHOTOPHYSICS and PHOTOCHEMISTRY OF BIS-2-(9-ANTHRYL)ETHYL GLUTARATE" @default.
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- W1993109935 doi "https://doi.org/10.1111/j.1751-1097.1990.tb01693.x" @default.
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