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• W1993119216 abstract "Zerovalent iron (Fe0, ZVI) has drawn great interest as an inexpensive and effective material to promote the degradation of environmental contaminants. A focus of ZVI research is to increase degradation kinetics and overcome passivation for long-term remediation. Halide ions promote corrosion, which can increase and sustain ZVI reactivity. Adding chloride or bromide salts with Fe0 (1% w/v) greatly enhanced TNT, RDX, and HMX degradation rates in aqueous solution. Adding Cl or Br salts after 24 h also restored ZVI reactivity, resulting in complete degradation within 8 h. These observations may be attributed to removal of the passivating oxide layer and pitting corrosion of the iron. While the relative increase in degradation rate by Cl− and Br− was similar, TNT degraded faster than RDX and HMX. HMX was most difficult to remove using ZVI alone but ZVI remained effective after five HMX reseeding cycles when Br− was present in solution." @default.
• W1993119216 created "2016-06-24" @default.
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• W1993119216 date "2007-06-01" @default.
• W1993119216 modified "2023-10-16" @default.
• W1993119216 title "Halide salts accelerate degradation of high explosives by zerovalent iron" @default.
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• W1993119216 doi "https://doi.org/10.1016/j.envpol.2006.10.010" @default.
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