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- W1993133092 abstract "Intermolecular benzylic methylene functionalization of exo-cyclic enol ethers has been achieved using imines as reagents and potassium tert-butoxide as the catalyst. Depending on the solvent used, the reaction proceeds by two pathways. In THF, an addition/elimination reaction of exo-cyclic enol ethers with imines provides dihydroisobenzofuran derivatives in good yield. In DMSO, an addition/ring-opening/cyclization cascade reaction occurs with unexpected cleavage of C–O and C–C bonds, affording isoquinolin-1(2H)-one products in high yield under ambient reaction conditions." @default.
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- W1993133092 date "2013-12-02" @default.
- W1993133092 modified "2023-09-27" @default.
- W1993133092 title "ChemInform Abstract: Solvent-Switched Benzylic Methylene Functionalization: Addition, Ring-Opening, Cyclization, and Unexpected Cleavage of C-O and C-C Bonds." @default.
- W1993133092 cites W2951512967 @default.
- W1993133092 doi "https://doi.org/10.1002/chin.201351174" @default.
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