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- W1993159647 abstract "Gas-phase pyrolysis reactions of 4(2′-dimethylaminoethenyl)-2-oxo-2H-benzo[b]pyran-3-carbonitrile (1), 4(2′-dimethylaminoethenyl)-2-oxo-2H-naphtho[1,2-b]pyran-3-carbonitrile (2), 1,6-dihydro-4-(2′-dimethylaminoethenyl)-6-oxo-1-phenylpyridazine-3,5-dicarbonitrile (3), 2-cyano-5-dimethylamino-3-phenyl-2,4-pentadienonitrile (4), 2-cyano-5-dimethylamino-3-(2-thienyl)-2,4-pentadienonitrile(5), 1,2-dihydro-4-(2′-dimethylaminoethenyl)-oxo-quinoline-4-carbonitrile (6), 6-(ethylthio)-4-(2′-dimethylaminoethenyl)-2-phenylpyrimidine-5-carbonitrile (7) (Scheme 1) have been carried out. The rates of gas-phase pyrolytic reactions of compounds 3, 4, 5, and 7 have been measured and found to correspond to unimolecular first-order reactions. Product analyses together with kinetic data were used to outline a feasible pathway for the pyrolytic reactions of the compounds under study. © 2001 John Wiley & Sons, Inc. Heteroatom Chem 12:47–51, 2001" @default.
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- W1993159647 date "2001-01-01" @default.
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- W1993159647 title "Gas-phase pyrolysis of 2-heteroaromatic-1-dimethylaminoethylenes: Kinetic and mechanistic study" @default.
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- W1993159647 doi "https://doi.org/10.1002/1098-1071(2001)12:1<47::aid-hc10>3.0.co;2-q" @default.
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