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- W1993165736 abstract "Bis(trimethylsilyl)bicyclo[n,1,0]alkanes react with acids, leading readily to substitution of one Me3Si group and/or opening of the three-carbon ring. The size of the larger ring (n value) plays a prominent role in the orientation of the reaction. The results can be rationalized by steric hindrance considerations. From a synthetic point of view, this study allows us to isolate new bis(trimethylsilyl)methylcycloalkenes and acetoxy- or chloro-bis(trimethylsilyl)methylcycloalkanes. L'action des acides sur les bis(triméthylsilyl)bicyclo[n,1,0]alcanes conduit à la substitution d'un groupe SiMe3 et/ou à l'ouverture du cycle à trois chaînons. La taille du grand cycle (valeur de n) joue un rôle déterminant sur l'orientation de la réaction. Des considérations d'ordre stérique permettent de rationnaliser l'ensemble de ces résultats. Sur le plan synthétique, cette étude a permis d'isoler des disilylméthylcyclènes et des disilylméthyl acétoxy- ou chlorocyclanes originaux." @default.
- W1993165736 created "2016-06-24" @default.
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- W1993165736 date "1985-02-01" @default.
- W1993165736 modified "2023-09-25" @default.
- W1993165736 title "Bis(trimethylsilyl)bicyclo[n,1,0]alcanes: Reactivite vis-a-vis des acides" @default.
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- W1993165736 doi "https://doi.org/10.1016/0022-328x(85)88108-0" @default.
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