FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1993227279> ?p ?o ?g. }

• W1993227279 endingPage "6287" @default.
• W1993227279 startingPage "6279" @default.
• W1993227279 abstract "We report experimentally determined first-order rate constants of MeHg photolysis in three waters along a Boreal lake-wetland gradient covering a range of pH (3.8–6.6), concentrations of total organic carbon (TOC 17.5–81 mg L–1), total Fe (0.8–2.1 mg L–1), specific UV254 nm absorption (3.3–4.2 L mg–1 m–1) and TOC/TON ratios (24–67 g g–1). Rate constants determined as a function of incident sunlight (measured as cumulative photon flux of photosynthetically active radiation, PAR) decreased in the order dystrophic lake > dystrophic lake/wetland > riparian wetland. After correction for light attenuation by dissolved natural organic matter (DOM), wavelength-specific (PAR: 400–700 nm, UVA: 320–400 nm and UVB: 280–320 nm) first-order photodegradation rate constants (kpd) determined at the three sites were indistinguishable, with average values (±SE) of 0.0023 ± 0.0002, 0.10 ± 0.024 and 7.2 ± 1.3 m2 E–1 for kpdPAR, kpdUVA, and kpdUVB, respectively. The relative ratio of kpdPAR, kpdUVA, and kpdUVB was 1:43:3100. Experiments conducted at varying MeHg/TOC ratios confirm previous suggestions that complex formation with organic thiol groups enhances the rate of MeHg photodegradation, as compared to when O and N functional groups are involved in the speciation of MeHg. We suggest that if the photon fluxes of PAR, UVA, and UVB radiation are separately determined and the wavelength-specific light attenuation is corrected for, the first-order rate constants kpdPAR, kpdUVA, and kpdUVB will be universal to waters in which DOM (possibly in concert with Fe) controls the formation of ROS, and the chemical speciation of MeHg is controlled by the complexation with DOM associated thiols." @default.
• W1993227279 created "2016-06-24" @default.
• W1993227279 creator A5014076471 @default.
• W1993227279 creator A5018008694 @default.
• W1993227279 creator A5020488635 @default.
• W1993227279 creator A5070191672 @default.
• W1993227279 creator A5070347699 @default.
• W1993227279 creator A5077772038 @default.
• W1993227279 creator A5082443618 @default.
• W1993227279 creator A5087052151 @default.
• W1993227279 date "2013-05-29" @default.
• W1993227279 modified "2023-10-08" @default.
• W1993227279 title "Towards Universal Wavelength-Specific Photodegradation Rate Constants for Methyl Mercury in Humic Waters, Exemplified by a Boreal Lake-Wetland Gradient" @default.
• W1993227279 cites W1532270673 @default.
• W1993227279 cites W1966682922 @default.
• W1993227279 cites W1966982915 @default.
• W1993227279 cites W1969508650 @default.
• W1993227279 cites W1969882744 @default.
• W1993227279 cites W1971556334 @default.
• W1993227279 cites W1975010088 @default.
• W1993227279 cites W1977884904 @default.
• W1993227279 cites W1978163322 @default.
• W1993227279 cites W1978541344 @default.
• W1993227279 cites W1981492787 @default.
• W1993227279 cites W1982842807 @default.
• W1993227279 cites W1985373671 @default.
• W1993227279 cites W2000438124 @default.
• W1993227279 cites W2006841525 @default.
• W1993227279 cites W2014506367 @default.
• W1993227279 cites W2018381431 @default.
• W1993227279 cites W2031070866 @default.
• W1993227279 cites W2033424633 @default.
• W1993227279 cites W2034055209 @default.
• W1993227279 cites W2034359475 @default.
• W1993227279 cites W2038019186 @default.
• W1993227279 cites W2040690011 @default.
• W1993227279 cites W2044861106 @default.
• W1993227279 cites W2045451666 @default.
• W1993227279 cites W2050734952 @default.
• W1993227279 cites W2056046833 @default.
• W1993227279 cites W2063482051 @default.
• W1993227279 cites W2065093525 @default.
• W1993227279 cites W2074196765 @default.
• W1993227279 cites W2091719706 @default.
• W1993227279 cites W2093336601 @default.
• W1993227279 cites W2099441540 @default.
• W1993227279 cites W2101380647 @default.
• W1993227279 cites W2116562890 @default.
• W1993227279 cites W2124041714 @default.
• W1993227279 cites W2126361636 @default.
• W1993227279 cites W2126689975 @default.
• W1993227279 cites W2127672368 @default.
• W1993227279 cites W2142544373 @default.
• W1993227279 cites W2152909857 @default.
• W1993227279 cites W2166608740 @default.
• W1993227279 cites W2169039330 @default.
• W1993227279 cites W2171568827 @default.
• W1993227279 cites W2327766428 @default.
• W1993227279 doi "https://doi.org/10.1021/es400373s" @default.
• W1993227279 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23647363" @default.
• W1993227279 hasPublicationYear "2013" @default.
• W1993227279 type Work @default.
• W1993227279 sameAs 1993227279 @default.
• W1993227279 citedByCount "56" @default.
• W1993227279 countsByYear W19932272792014 @default.
• W1993227279 countsByYear W19932272792015 @default.
• W1993227279 countsByYear W19932272792016 @default.
• W1993227279 countsByYear W19932272792017 @default.
• W1993227279 countsByYear W19932272792018 @default.
• W1993227279 countsByYear W19932272792019 @default.
• W1993227279 countsByYear W19932272792020 @default.
• W1993227279 countsByYear W19932272792021 @default.
• W1993227279 countsByYear W19932272792022 @default.
• W1993227279 countsByYear W19932272792023 @default.
• W1993227279 crossrefType "journal-article" @default.
• W1993227279 hasAuthorship W1993227279A5014076471 @default.
• W1993227279 hasAuthorship W1993227279A5018008694 @default.
• W1993227279 hasAuthorship W1993227279A5020488635 @default.
• W1993227279 hasAuthorship W1993227279A5070191672 @default.
• W1993227279 hasAuthorship W1993227279A5070347699 @default.
• W1993227279 hasAuthorship W1993227279A5077772038 @default.
• W1993227279 hasAuthorship W1993227279A5082443618 @default.
• W1993227279 hasAuthorship W1993227279A5087052151 @default.
• W1993227279 hasConcept C107872376 @default.
• W1993227279 hasConcept C121332964 @default.
• W1993227279 hasConcept C135009316 @default.
• W1993227279 hasConcept C142796444 @default.
• W1993227279 hasConcept C148898269 @default.
• W1993227279 hasConcept C161790260 @default.
• W1993227279 hasConcept C162847780 @default.
• W1993227279 hasConcept C178790620 @default.
• W1993227279 hasConcept C185592680 @default.
• W1993227279 hasConcept C18903297 @default.
• W1993227279 hasConcept C199360897 @default.
• W1993227279 hasConcept C2777777548 @default.
• W1993227279 hasConcept C2780892065 @default.
• W1993227279 hasConcept C36574619 @default.
• W1993227279 hasConcept C41008148 @default.

• next