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- W1993279681 abstract "The behaviour of [36Cl]-chlorine and [14C]-carbon labelled carbon tetrachloride at 500 K and of [36Cl]-chlorine and [2H]-hydrogen labelled anhydrous hydrogen chloride at 293 K towards calcined γ-alumina has been investigated under static conditions. Two types of surface chlorine species are formed using CCl4; one type is inert with respect to [36Cl]-chlorine exchange with anhydrous HCl at 293 K, the other is labile and behaves identically to the surface species resulting from treatment with HCl. Radiotracer and neutron activation analyses indicate that more chlorine is retained by samples treated with CCl4 under the conditions used. The results of isotopic exchange reactions together with an examination of the CCl4 reaction using IR spectroscopy and 27Al MAS NMR spectra of chlorinated γ-alumina are used to make proposals about the nature of the acidic sites formed." @default.
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- W1993279681 date "1991-07-01" @default.
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- W1993279681 title "Halogen-promoted γ-alumina I. The interactions of 36Cl- and 14C-labelled carbon tetrachloride and of 36Cl- and 2H-labelled hydrogen chloride with γ-alumina" @default.
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- W1993279681 doi "https://doi.org/10.1016/0304-5102(91)85038-4" @default.
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