Matches in SemOpenAlex for { <https://semopenalex.org/work/W1993281016> ?p ?o ?g. }
Showing items 1 to 89 of
89
with 100 items per page.
- W1993281016 abstract "Reactions of methylbismuth(III) dichloride with thiosemicarbazones (TSC) in 1:1 and 1:2 molar ratios in anhydrous methanol yield [MeBiCl2.n{RR’CNNHCSNH2}] [where, R=R’=CH3 and n=1 (1) or n=2 (2); R=C6H4OH, R’=H and n=1 (3) or n=2 (4); R=C5H4N, R’=CH3 and n=1 (5) or n=2 (6)]. These monomeric adducts have been characterized by elemental analyses, Fourier transform infrared, nuclear magnetic resonance [1H, 13C{1H}] and fast atom bombardment mass spectrometry. The ligand appears to bind bismuth through sulfur and azomethine nitrogen atoms rendering penta- and hepta- coordination geometries, in (1, 3 and 5) and (2, 4 and 6), respectively, in the solution state. Low temperature (143–145°C) solvothermal transformation of (3) or (4) in refluxing xylene yields nano-structured flowers of amorphous bismuthinite (Bi2S3). Prolonged (~10 h) sintering at 150°C of the powder obtained from (4) yielded one-dimensional micro/nanorods of orthorhombic Bi2S3. All the materials were characterized by X-ray diffraction, scanning electron microscopy and energy-dispersive X-ray analyses." @default.
- W1993281016 created "2016-06-24" @default.
- W1993281016 creator A5004855784 @default.
- W1993281016 creator A5007848830 @default.
- W1993281016 creator A5064357057 @default.
- W1993281016 creator A5091874089 @default.
- W1993281016 date "2011-01-01" @default.
- W1993281016 modified "2023-09-24" @default.
- W1993281016 title "Synthesis and characterization of thiosemicarbazone derivatives of methylbismuth(III) dichloride: generation of one dimensional micro-rods of bismuthinite from [MeBiCl2·n{(C6H4OH)CHNNHCSNH2}] by a solvothermal process" @default.
- W1993281016 cites W143539683 @default.
- W1993281016 cites W1490325333 @default.
- W1993281016 cites W1517748388 @default.
- W1993281016 cites W1968272229 @default.
- W1993281016 cites W1971267211 @default.
- W1993281016 cites W1988392433 @default.
- W1993281016 cites W2008172222 @default.
- W1993281016 cites W2009543312 @default.
- W1993281016 cites W2016042392 @default.
- W1993281016 cites W2019388060 @default.
- W1993281016 cites W2032309930 @default.
- W1993281016 cites W2035676210 @default.
- W1993281016 cites W2038304044 @default.
- W1993281016 cites W2039104028 @default.
- W1993281016 cites W2040455495 @default.
- W1993281016 cites W2043427526 @default.
- W1993281016 cites W2055025505 @default.
- W1993281016 cites W2056121690 @default.
- W1993281016 cites W2057027833 @default.
- W1993281016 cites W2070461478 @default.
- W1993281016 cites W2072652448 @default.
- W1993281016 cites W2115712203 @default.
- W1993281016 cites W2120971982 @default.
- W1993281016 cites W2161134206 @default.
- W1993281016 cites W2331908667 @default.
- W1993281016 cites W2333474345 @default.
- W1993281016 cites W4229778211 @default.
- W1993281016 cites W4233197131 @default.
- W1993281016 doi "https://doi.org/10.1515/mgmc.2011.016" @default.
- W1993281016 hasPublicationYear "2011" @default.
- W1993281016 type Work @default.
- W1993281016 sameAs 1993281016 @default.
- W1993281016 citedByCount "0" @default.
- W1993281016 crossrefType "journal-article" @default.
- W1993281016 hasAuthorship W1993281016A5004855784 @default.
- W1993281016 hasAuthorship W1993281016A5007848830 @default.
- W1993281016 hasAuthorship W1993281016A5064357057 @default.
- W1993281016 hasAuthorship W1993281016A5091874089 @default.
- W1993281016 hasConcept C115624301 @default.
- W1993281016 hasConcept C126201875 @default.
- W1993281016 hasConcept C13965031 @default.
- W1993281016 hasConcept C171250308 @default.
- W1993281016 hasConcept C178790620 @default.
- W1993281016 hasConcept C185592680 @default.
- W1993281016 hasConcept C192562407 @default.
- W1993281016 hasConcept C2776011623 @default.
- W1993281016 hasConcept C2779607525 @default.
- W1993281016 hasConcept C37243968 @default.
- W1993281016 hasConcept C8010536 @default.
- W1993281016 hasConceptScore W1993281016C115624301 @default.
- W1993281016 hasConceptScore W1993281016C126201875 @default.
- W1993281016 hasConceptScore W1993281016C13965031 @default.
- W1993281016 hasConceptScore W1993281016C171250308 @default.
- W1993281016 hasConceptScore W1993281016C178790620 @default.
- W1993281016 hasConceptScore W1993281016C185592680 @default.
- W1993281016 hasConceptScore W1993281016C192562407 @default.
- W1993281016 hasConceptScore W1993281016C2776011623 @default.
- W1993281016 hasConceptScore W1993281016C2779607525 @default.
- W1993281016 hasConceptScore W1993281016C37243968 @default.
- W1993281016 hasConceptScore W1993281016C8010536 @default.
- W1993281016 hasIssue "3-4" @default.
- W1993281016 hasLocation W19932810161 @default.
- W1993281016 hasLocation W19932810162 @default.
- W1993281016 hasOpenAccess W1993281016 @default.
- W1993281016 hasPrimaryLocation W19932810161 @default.
- W1993281016 hasRelatedWork W1983374171 @default.
- W1993281016 hasRelatedWork W2026383304 @default.
- W1993281016 hasRelatedWork W2108121134 @default.
- W1993281016 hasRelatedWork W2163421117 @default.
- W1993281016 hasRelatedWork W2236098506 @default.
- W1993281016 hasRelatedWork W2357178580 @default.
- W1993281016 hasRelatedWork W2563756205 @default.
- W1993281016 hasRelatedWork W27907731 @default.
- W1993281016 hasRelatedWork W288675336 @default.
- W1993281016 hasRelatedWork W2985657003 @default.
- W1993281016 hasVolume "34" @default.
- W1993281016 isParatext "false" @default.
- W1993281016 isRetracted "false" @default.
- W1993281016 magId "1993281016" @default.
- W1993281016 workType "article" @default.