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- W1993288956 abstract "Photochemistry of Sm3+ has been studied by means of the nanosecond laser flash photolysis using a KrF excimer laser with the oscillation wavelength of 248 nm. Samples were an air-saturated methanol solution of SmCl3 and that of SmBr3. It is found that the photoreduction of Sm3+ to Sm2+ is induced in the methanol solution of SmCl3 and the photoreduction yield at 100 ns after the laser irradiation and the lifetime of Sm2+ are estimated to be 0.29 ± 0.06 and 5.2 ± 0.7 μs, respectively. In the photolysis of the methanol solution of SmBr3, a solvated electron, esol− and Br2− were formed." @default.
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- W1993288956 date "2006-02-01" @default.
- W1993288956 modified "2023-09-27" @default.
- W1993288956 title "Photochemistry of SmCl3 and SmBr3 in air-saturated methanol solution" @default.
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- W1993288956 doi "https://doi.org/10.1016/j.jallcom.2005.01.087" @default.
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